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词汇 carbonium ion
释义

Definition of carbonium ion in English:

carbonium ion

nounkɑːˈbəʊnɪəm ˌʌɪənkɑrˌboʊniəm ˈaɪˌɑn
Chemistry
  • An organic cation in which the positive charge is located on a carbon atom.

    〔化〕正碳离子,阳碳离子

    Example sentencesExamples
    • If a carbonium ion is involved in lysozyme catalysis then the TS structure will involve a planar, sp-hybridized C - 1.
    • The key step in a unimolecular reaction is the formation of the carbon cation, or carbonium ion, by the departure of the leaving group.
    • This paper reviews the concept of carbonium ions, their formation, stability and reactions.
    • Geometry optimisation using density function theory at the pBP / DN - level shows the carbonium ion to be trigonal bipyramidal.
    • The presence of a water molecule will provide the opportunity for the carbonium ion, and the left side of the ring, to become stable.

Origin

Early 20th century: carbonium from carbo- 'carbon', on the pattern of ammonium.

Definition of carbonium ion in US English:

carbonium ion

nounkärˌbōnēəm ˈīˌänkɑrˌboʊniəm ˈaɪˌɑn
Chemistry
  • An organic cation in which the positive charge is located on a carbon atom.

    〔化〕正碳离子,阳碳离子

    Example sentencesExamples
    • The presence of a water molecule will provide the opportunity for the carbonium ion, and the left side of the ring, to become stable.
    • Geometry optimisation using density function theory at the pBP / DN - level shows the carbonium ion to be trigonal bipyramidal.
    • This paper reviews the concept of carbonium ions, their formation, stability and reactions.
    • If a carbonium ion is involved in lysozyme catalysis then the TS structure will involve a planar, sp-hybridized C - 1.
    • The key step in a unimolecular reaction is the formation of the carbon cation, or carbonium ion, by the departure of the leaving group.

Origin

Early 20th century: carbonium from carbo- ‘carbon’, on the pattern of ammonium.

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